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One Piece: 2x66
All Out Battle! Luffy vs. Zoro, Mysterious Grand Duel!
Luffy, who does not realize the town is full of bounty hunters, engages in a battle with Zoro after he discovers that Zoro attacked the townsfolk, while Mr. 5 and Miss Valentine head for Princess Vivi.
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2 - 66All Out Battle! Luffy vs. Zoro, Mysterious Grand Duel! Apr. 22, 2001
2 - 67Deliver Princess Vivi! The Luffy Pirates Set Sail! Apr. 29, 2001
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2 - 70An Ancient Island! The Shadow Hiding in Little Garden! May. 27, 2001
2 - 71Huge Duel! The Giants Dorry and Broggy! Jun. 03, 2001
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2 - 74The Devilish Candle! Tears of Regret and Tears of Anger! Jul. 15, 2001
2 - 75A Hex on Luffy! Colors Trap! Aug. 12, 2001
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2 - 77Farewell Giant Island! Head for Alabasta! Aug. 19, 2001